Synthesis of a novel planar-chiral nido-carborane amino acid
نویسندگان
چکیده
The deboronation of enantiomers planar-chiral benzyl (3-formamido-1,2-dicarba-closo-dodecaboran-1-yl)acetate gave the individual (RP)- and (SP)-enantiomers (ee > 98%) a new amino acid containing nido-carborane fragment, (3-ammonio-7,8-dicarba-nido-undecaboran-7-yl)acetic acid. Chiral HPLC methods for analysis enantiomeric purity this compound was developed.
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ژورنال
عنوان ژورنال: Russian Chemical Bulletin
سال: 2021
ISSN: ['1573-9171', '1066-5285']
DOI: https://doi.org/10.1007/s11172-021-3121-7